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81.
Shunlong Luo 《Theoretical and Mathematical Physics》2008,155(3):896-904
By regarding quantum states as communication channels and using observable correlations quantitatively expressed by mutual
information, we introduce a hierarchy of entanglement measures that includes the entanglement of formation as a particular
instance. We compare the maximal and minimal measures and indicate the conceptual advantages of the minimal measure over the
entanglement of formation. We reveal a curious feature of the entanglement of formation by showing that it can exceed the
quantum mutual information, which is usually regarded as a theoretical measure of total correlations. This places the entanglement
of formation in a broader scenario, highlights its peculiarity in relation to pure-state ensembles, and introduces a competing
definition with intrinsic informational significance.
__________
Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 155, No. 3, pp. 453–462, June, 2008. 相似文献
82.
Binary mutual diffusion coefficients D can be estimated from the width at half height W
1/2 of Taylor dispersion profiles using D=(ln 2)r
2
t
R/(3W
2
h) and values of the retention time t
R and dispersion tube radius r. The generalized expression D
h=−(ln h)r
2
t
R/(3W
2
h
) is derived to evaluate diffusion coefficients from peak widths W
h
measured at other fractional heights (e.g., (h = 0.1, 0.2,…,0.9). Tests show that averaging the D
h
values from binary profiles gives mutual diffusion coefficients that are as accurate and precise as those obtained by more
elaborate nonlinear least-squares analysis. Dispersion profiles for ternary solutions usually consist of two superimposed
pseudo-binary profiles. Consequently, D
h
values for ternary profiles generally vary with the fractional peak height h. Ternary profiles with constant D
h
values can however be constructed by taking appropriate linear combinations of profiles generated using different initial
concentration differences. The invariant D
h
values and corresponding initial concentration differences give the eigenvalues and eigenvectors for the evaluation of the
ternary diffusion coefficient matrix. Dispersion profiles for polymer samples of N i-mers consist of N superimposed pseudo-binary profiles. The edges of these profiles are enriched in the heavier polymers owing to the decrease
in polymer diffusion coefficients with increasing polymer molecular weight. The resulting drop in D
h
with decreasing fractional peak height provides a signature of the polymer molecular weight distribution. These features
are illustrated by measuring the dispersion of mixed polyethylene glycols. 相似文献
83.
84.
Yilmaz Yurekli Sacide Alsoy Altinkaya John M. Zielinski 《Journal of Polymer Science.Polymer Physics》2007,45(15):1996-2006
Mutual diffusion coefficients and sorption isotherms of methyl methacrylate (MMA) and butyl acrylate (BA) monomers in methyl methacrylate‐butyl acrylate copolymer (MMA‐BA) have been measured by gravimetric sorption. MMA is found to have higher solubility and diffusion rates in the copolymer than BA. Sorption data for MMA were interpreted using classical Flory‐Huggins thermodynamic theory with a constant interaction parameter (χ). A modified version of this theory has been applied to correlate the sorption data of BA, which exhibit a temperature and concentration‐dependent χ parameter. For MMA, the isotherm data reveal enhanced polymer‐solvent interactions with increasing temperature, while for BA the data indicate a drive toward phase separation with increasing temperature. Despite the difference in thermodynamic behavior, both monomers are found to exhibit Fickian diffusion and the diffusivity data are correlated reasonably well with the Vrentas‐Duda free volume theory. Some deviation between the free‐volume correlation and the experimental data is observed at the lowest temperature and BA concentration examined. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1996–2006, 2007 相似文献
85.
Representation of Multicomponent Liquid-Liquid Equilibria for Aqueous and Organic Solutions Using a Modified UNIQUAC Model 总被引:6,自引:0,他引:6
Kazuhiro Tamura Yao Chen Kaoru Tada Toshiro Yamada Isamu Nagata 《Journal of solution chemistry》2000,29(5):463-488
A modified form of the UNIQUAC model is presented to accurately reproducebinary phase equilibria and ternary and quaternary liquid-liquid equilibria ofaqueous and organic solutions. The model gives a good representation in thereproduction of binary coexistence curves over a wide temperature range usingtemperature-dependent parameters and of binary vapor-liquid equilibria usingtwo binary energy parameters, and in the correlation of ternary and quaternaryliquid-liquid equilibria using ternary and quaternary parameters, in addition tobinary parameters. The quaternary calculated results are compared with thoseobtained from the modified Wilson and extended UNIQUAC models. 相似文献
86.
87.
This article investigates the behavior of a Moshinsky atom in a 1D harmonic trap. Focus is given on the theoretical foundations of confinement and its impact on the correlation between particles in the Moshinsky atom. The investigation begins by illustrating the (de)localization of the probability density function using Shannon entropy. The basics of correlation and interpretation of correlation using tools such as mutual information and statistical correlation coefficients and how these can be quantified are discussed. Then the concept of confinement is explored. The impact of interaction strength and confinement on Shannon entropy, statistical correlation coefficients, and mutual information is investigated. How interaction strength and confinement can be used to induce correlations between previously uncorrelated particles, as well as how they can be used to suppress correlations between previously correlated particles is discussed. Their implications for quantum information processing and quantum simulation are discussed. In conclusion, confinement is a powerful tool for controlling correlations in quantum systems, and its impact on correlation can be understood through theoretical models. The importance of experimental studies in this field, which provide insights into the behavior of quantum systems under confinement and pave the way for future applications in quantum technology is also emphasized. 相似文献
88.
从基金管理者的角度出发,引入了一种开放式基金预留现金和债券比例管理模型,它可以使满足及时赎回需求概率很大且预留现金和债券最少.使用二元Archimedean Copula分析了预留现金和债券比例的计算公式,通过数值实例分析了预留比例公式的合理性,为基金管理人制定投资目标时随时控制预留现金的比例,提供一个参考的标准. 相似文献
89.
90.
利用均值-方差模型,分析了非线性交易成本下的共同基金与无风险资产投资组合的有效边界和在一般的效用函数下讨论了投资者的最优投资策略. 相似文献